The monoclinic form of di-μ-aqua-bis[diaquabis(thiocyanato-κN)iron(II)]–1,4-bis(4H-1,2,4-triazol-4-yl)benzene (1/3)
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چکیده
The title complex, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), comprises two Fe(II) atoms octahedrally coordinated and bridged by two aqua O atoms that straddle a crystallographic inversion center, forming a quadrilateral core. The water ligands of the core are involved in hydrogen bonds with the triazole N atoms of the organic mol-ecules, which generates a layer motif in the ab plane. There are π-π stacking inter-actions between benzene rings of 3.490 (6) Å, and between triazole rings of 3.543 (8) and 3.734 (7) Å in neighboring layers, forming a three-dimensional network.
منابع مشابه
The triclinic form of di-μ-aqua-bis[diaquabis(thiocyanato-κN)iron(II)]–1,4-bis(4H-1,2,4-triazol-4-yl)benzene (1/3)
In the title compound, [Fe(2)(NCS)(4)(H(2)O)(6)]·3C(10)H(8)N(6), the centrosymmetric dinuclear complex contains two Fe(II) ions bridged by two aqua ligand O atoms, forming a four-membered ring. The slightly distorted octa-hedral coordination environment of the two Fe(II) ions is completed by two monodentate aqua ligands and two thio-cyanate ligands. One of the 1,4-bis-(4H-1,2,4-triazol-4-yl)ben...
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